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April 1, 2024
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Обновлено 14 фев 2018
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linda
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События
1832 Cyanide ion catalyzed Benzoin condensation, Lieblig, Wöhler
1971 Hajos Parrish - reaction, catalyzed by proline, first asymmetric synthesis with organocatalyst
2000 List/MacMillan introduces organocatalysis field
1943 Ukai, thiazolium salt - benzoin (did not know what catalyzed)
1958 Breslow find thiamine cat benzoin - Carbene identified
1988 Bertrand - isolation of phosphinocarbene
1991 Arduengo - isolation of imidazolylidene
2004Glorious and Bode, Rovis - alpha-function aldehydes --> acylation reagents (Internal redox) NHC
1960 Wanzlick - dimerization of NHC
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